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From shrimp to steel: Introducing nature-inspired metalworking
Metallic duplicate of a honeybee’s (Apis mellifera) head, created at room temperature and strain, utilizing the identical rules bugs use to kind their exoskeleton. Credit score: SUTD

People have lengthy turned to nature for options, from deciphering the mysteries of flight to creating stronger supplies. For Javier Fernandez, Affiliate Professor on the Singapore College of Know-how and Design (SUTD), nature is a blueprint for sustainability. “Not like our society’s energy-intensive engineering, nature operates beneath a paradigm of shortage and finds options with out entry to intense power sources or transport of supplies,” he noticed.

Chitin, discovered in every single place in nature, starting from shrimp to seashells and mushrooms, is an natural materials that deserves a more in-depth look. Along with being the second most ample on Earth, it’s robust and light-weight, making it a super materials for a lot of engineering purposes.

“Chitin additionally has a robust affinity for metals,” stated Assoc Prof Fernandez. “We determined to guage whether or not this affinity, mixed with the processes that form the cuticle, might be used to supply useful metallic constructions in a ‘organic’ method.”

Within the pure world, metals, whereas hardly ever used, will be present in some chitinous constructions, such because the cuticles and exoskeletons of bugs and crustaceans. By digging deeper into the affinity that chitins and their derivatives have for metals, Fernandez and his workforce designed a brand new method to metalworking, which they revealed of their paper, “A organic method to metalworking based mostly on chitinous colloids and composites,” within the journal Superior Purposeful Supplies.

Via the usage of design and know-how impressed by these chitinous compounds, the analysis workforce demonstrated a novel method of manufacturing useful metallic constructions with out the standard power prices.

In conventional metalworking, excessive temperatures and pressures are important to soften and form metals. This stands in stark distinction to how metals are included into chitinous supplies in nature, which occurs beneath ambient circumstances.

Take the metallic compounds present in arthropod cuticles like crab shells, for instance. Sometimes, the metals solely make their method into the crab shell on the later phases of chitin improvement—the chitin would first stiffen right into a shell by way of tanning and dehydration earlier than any from the setting will get added to it.

That is just like how steel compounds may also be launched to chitosan, a by-product of chitin, because the researchers found of their experiments. They had been capable of kind stable metallic composites beneath commonplace temperature and strain simply by introducing very small quantities of chitosan and water between particles of various metals.

When the water evaporates, the chitosan molecules replicate the consolidation course of within the cuticles, pulling the particles along with such energy that they turn out to be a steady stable of 99.5% steel.

Fernandez likens the fabrication course of to concrete formation, explaining, “By pouring steel particles into dissolved chitosan and letting them ‘dry,’ we will kind huge metallic components with out the constraints of melting.”

Whereas these chitometallic composites weren’t bodily robust, the researchers discovered that the fabric acquired good electrical conductivity and might be 3D-printed. On the similar time, the fabric continued to indicate compatibility with different biomaterials regardless of solely containing a small quantity of chitosan. This opens up the potential of introducing these chitometallic properties into different biomaterials, similar to wooden and cellulose.

Fernandez believes this know-how creates a brand new paradigm of metalworking. Regardless of the dearth of mechanical energy, the fabricated biomaterial is appropriate for non-load-bearing metallic elements, similar to electrical elements or battery electrodes. Metalwork for some elements can now be carried out with out being resource-intensive.

“This know-how doesn’t change conventional strategies however allows new complementary manufacturing strategies,” he emphasised.

Since then, Fernandez’s workforce has efficiently filed a patent for the modern fabrication methodology and is now trying into designing a brand new know-how to develop biodegradable 3D digital elements, which might pave the way in which for extra environment friendly and sustainable strategies of manufacturing.

Extra info:
Shiwei Ng et al, A Organic Strategy to Metalworking Based mostly on Chitinous Colloids and Composites, Superior Purposeful Supplies (2024). DOI: 10.1002/adfm.202406800

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